Synthesis and crystal structures of 2,3,12,13-tetraalkoxy-21,23-dithiaporphyrins and 2,3-dialkoxy-21-monothiaporphyrins

نویسندگان

  • Neeraj Agarwal
  • C.-H. Hung
  • Mangalampalli Ravikanth
چکیده

The tetraalkoxy and dialkoxy substituted 21,23-dithiaporphyrins and 21-monothiaporphyrins, respectively, having methoxy, butoxy, octyloxy and dodecyloxy substituents at b-thiophene carbons were synthesized and characterized. The X-ray structure was solved for tetrabutoxy substituted 21,23-dithiaporphyrin and it exhibited a more planar structure compared with unsubstituted S2TPP, whereas the dimethoxy substituted 21-monothiaporphyrin showed a saddle shaped structure similar to unsubstituted STPPH.

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تاریخ انتشار 2004